{"72771":{"#nid":"72771","#data":{"type":"news","title":"Researchers Find Controls to Gold Nanocatalysis","body":[{"value":"\u003Cp\u003EResearchers at the Georgia Institute of Technology have made a discovery that could allow scientists to exercise more control over the catalytic activity of gold nanoclusters. The finding - that the dimensionality and structure, and thus the catalytic activity, of gold nanoclusters changes as the thickness of their supporting metal-oxide films is varied - is an important one in the rapidly developing field of nanotechnology. This and further advances in nanocatalysis may lead to lowering the cost of manufacturing materials from plastics to fertilizers. The research appeared in the July 21, 2006 issue of the journal Physical Review Letters.\u003C\/p\u003E\n\u003Cp\u003E\u0022We\u0027ve been searching for methods for controlling and tuning the nanocatalytic activity of gold nanoclusters,\u0022 said Uzi Landman, director of the Center for Computational Materials Science and Regents\u0027 professor and Callaway chair of physics at Georgia Tech. \u0022I believe the effect we discovered, whereby the structure and dimensionality of supported gold nanoclusters can be influenced and varied by the thickness of the underlying magnesium-oxide film may open new avenues for controlled nanocatalytic activity,\u0022 he said.\n\u003C\/p\u003E\n\u003Cp\u003ELandman\u0027s research group has been exploring the catalytic properties of gold, which is inert in its bulk form, for about seven years. In 1999, along with the experimental group of Ueli Heiz and Wolf-Dieter Schneider at the University of Lausanne, Landman\u0027s group showed that gold exhibits remarkable catalytic capabilities to speed the rate of chemical reactions if it is clustered in groups of eight to about two dozen atoms in size.\n\u003C\/p\u003E\n\u003Cp\u003ELast year in the journal Science, the teams of Landman and Heiz (now at the Technical University of Munich) showed that this catalytic activity involves defects, in the form of missing oxygen atoms, in the catalytic bed on which the gold clusters rest. These defect sites, referred to as F-centers, serve as sites for the gold to anchor itself, giving the gold clusters a slight negative charge. The charged gold transfers an electron to the reacting molecules, weakening the chemical bonds that keep them together. Once the bond is sufficiently weakened, it may be broken, allowing reactions to occur between the adsorbed reactants.\n\u003C\/p\u003E\n\u003Cp\u003ENow Landman\u0027s group has found that by using a thin catalytic bed with a thickness of up to 1 nanometer (nm), or 4-5 layers, of magnesium oxide, one may activate the gold nanoclusters which may act then as catalysts even if the bed is defect-free. A model reaction tested in these studies is one where carbon monoxide and molecular oxygen combine to form carbon dioxide, even at low temperatures. In these reactions, the bond connecting the two atoms in the adsorbed oxygen molecule weakens, thus, promoting the reaction with CO.\u003C\/p\u003E\n\u003Cp\u003EIn this study, Landman and company simulated the behavior of gold nanoclusters containing eight, sixteen and twenty atoms when placed on catalytic beds of magnesium oxide with a molybdenum substrate supporting the magnesium oxide film. Quantum mechanical calculations showed that when the magnesium oxide film was greater than 5 layers or 1 nm in thickness, the gold cluster kept its three-dimensional structure. However, when the film was less than 1nm, the cluster changed its structure and lied flat on the magnesia bed - wetting and adhering to it.\n\u003C\/p\u003E\n\u003Cp\u003EThe gold flattens because the electronic charge from the molybdenum penetrates through the thin layer of magnesium oxide and accumulates at the region where the gold cluster is anchored to the magnesium oxide. With a negative charge underneath the gold nanocluster, its attraction to the molybdenum substrate, located under the magnesia film, causes the cluster to collapse.\n\u003C\/p\u003E\n\u003Cp\u003E\u0022It\u0027s the charge that controls the adhesive strength of gold to the magnesia film, and at the same time it makes gold catalytically active,\u0022 said Landman. \u0022When you have a sufficiently thin layer of magnesium oxide, the charge from the underlying metal penetrates through - all the way to the interface of the gold cluster.\u0022\n\u003C\/p\u003E\n\u003Cp\u003EIn the previous experimental studies, defects in the magnesium oxide were required to bring about charging of the adsorbed clusters. \n\u003C\/p\u003E\n\u003Cp\u003E\u0022Until now, the metal substrate was regarded only as an experimental necessity for growing the magnesium oxide films on top of it. Now we found that it can be used as a design feature of the catalytic system. This field holds many surprises,\u0022 said Landman.\n\u003C\/p\u003E\n\u003Cp\u003ELandman\u0027s group is currently undertaking further explorations into possibilities to regulate the charge, and hence the catalytic activity, in gold nanocatalytic systems.\n\u003C\/p\u003E\n\u003Cp\u003ELandman and Heiz\u0027s book titled \u0022Nanocatalysis\u0022 is scheduled to be published this month.\n\u003C\/p\u003E\n\u003Cp\u003EThe current research was performed at the Center for Computational Materials Science by postdoctoral fellows Davide Ricci and Angelo Bongiorno under the supervision of Landman. The research team also included Dr. Gianfranco Pacchioni, a colleague from the University of Milano.\n\u003C\/p\u003E\n\u003Cp\u003EThe research appearing in the journal Science in 2005 was led by Landman and Heiz with Research Scientist Bokwon Yoon of the Center for Computational Materials Science as lead author.\n\u003C\/p\u003E\n\u003Cp\u003E\u003Cstrong\u003EFigure Caption:\u003C\/strong\u003E\u003Cbr \/\u003E\nStructures of a gold cluster (yellow) containing 20 atoms, adsorbed on a magnesium oxide bed ( magnesium in green and oxygen in red)  which is itself supported on top of a molybdenum substrate (blue).  The two-dimensional structure  is more stable by 3.3 eV than the three-dimensional structure. The excess electronic charge at the interface is shown in and the charge depletion is shown in light blue. The net accumulated interfacial charge equals 0.3e for the less stable, pyramidal structure on the left, and it increases to 1.0e for the stable planar structure shown on the right.\u003C\/p\u003E","summary":null,"format":"limited_html"}],"field_subtitle":"","field_summary":[{"value":"Researchers at the Georgia Institute of Technology have made a discovery that could allow scientists to exercise more control over the catalytic activity of gold nanoclusters, an important development in the rapidly developing field of nanotechnology.","format":"limited_html"}],"field_summary_sentence":[{"value":"Study shows catalytic activity of gold can be tuned"}],"uid":"27310","created_gmt":"2006-08-08 00:00:00","changed_gmt":"2016-10-08 03:02:23","author":"David Terraso","boilerplate_text":"","field_publication":"","field_article_url":"","dateline":{"date":"2006-08-08T00:00:00-04:00","iso_date":"2006-08-08T00:00:00-04:00","tz":"America\/New_York"},"extras":[],"hg_media":{"72772":{"id":"72772","type":"image","title":"Gold cluster","body":null,"created":"1449177954","gmt_created":"2015-12-03 21:25:54","changed":"1475894663","gmt_changed":"2016-10-08 02:44:23"},"72773":{"id":"72773","type":"image","title":"Gold cluster","body":null,"created":"1449177954","gmt_created":"2015-12-03 21:25:54","changed":"1475894663","gmt_changed":"2016-10-08 02:44:23"}},"media_ids":["72772","72773"],"related_links":[{"url":"http:\/\/www.physics.gatech.edu\/people\/faculty\/ulandman.html","title":"Uzi Landman"}],"groups":[{"id":"1214","name":"News Room"}],"categories":[],"keywords":[],"core_research_areas":[],"news_room_topics":[],"event_categories":[],"invited_audience":[],"affiliations":[],"classification":[],"areas_of_expertise":[],"news_and_recent_appearances":[],"phone":[],"contact":[{"value":"\u003Cp\u003E\u003Cstrong\u003EGeorgia Tech Media Relations\u003C\/strong\u003E\u003Cbr \/\u003ELaura Diamond\u003Cbr \/\u003E\u003Ca href=\u0022mailto:laura.diamond@comm.gatech.edu\u0022\u003Elaura.diamond@comm.gatech.edu\u003C\/a\u003E\u003Cbr \/\u003E404-894-6016\u003Cbr \/\u003EJason Maderer\u003Cbr \/\u003E\u003Ca href=\u0022mailto:maderer@gatech.edu\u0022\u003Emaderer@gatech.edu\u003C\/a\u003E\u003Cbr \/\u003E404-660-2926\u003C\/p\u003E","format":"limited_html"}],"email":["david.terraso@comm.gatech.edu"],"slides":[],"orientation":[],"userdata":""}}}